| Dec 11, 2025 |
Researchers have modelled how a new graphene-based membrane material could cut the energy use and cost of capturing CO2 from power and industrial plants.
(Nanowerk News) Carbon capture is becoming essential for industries that still depend on fossil fuels, including the cement and steel industries. Natural-gas power plants, coal plants, and cement factories all release large amounts of CO₂, and reducing those emissions is difficult without dedicated capture systems. Today, most plants rely on solvent-based systems that absorb CO₂, but these setups use a lot of heat, require major infrastructure, and can be costly to run.
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A smaller, electricity‑driven alternative is what the field calls a “membrane” system. A membrane works like an ultra‑fine filter that lets certain gases slip through more easily than others, separating CO₂ from the rest of the flue gas. The problem is that many membranes lose efficiency when CO₂ levels are low, which is common in natural‑gas plants, and this limits where they can be used.
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A new study at EPFL has now analyzed how a new membrane material, pyridinic‑graphene, could work at scale. This is a single‑layer graphene sheet with tiny pores that favor CO₂ over other gases. The researchers combined experimental performance data with modelling tools that simulate real operating conditions, such as energy use and gas flow. They also explored a wide range of cost scenarios to see how the material might behave once deployed in commercial plants.
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The study was led by Marina Micari and Kumar Varoon Agrawal who holds the Gaznat Chair in Advanced Separations at EPFL. It is published in Nature Sustainability (“Energy- and cost-efficient CO₂ capture from dilute emissions by pyridinic-graphene membranes”), and builds on the group’s previous research in developing scalable graphene membranes (Nature Chemical Engineering, “Scalable synthesis of CO₂-selective porous single-layer graphene membranes”).
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“As we are scaling up the technology, it is important to understand the implications on reduction on energy use and cost of carbon capture in the diverse sector of carbon capture,” says Agrawal. “This work address this.”
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| A graphene membrane separating CO2 from N2. (Image: EPFL, Ivan Savicev)
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Modeling shows where the membrane performs best
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The team tested different graphene-based membranes, including the pyridinic-graphene membrane, under several plant setups to compare how they would perform in real conditions. For natural-gas power stations, a three-step system that starts by enriching the CO₂ stream reached promising costs, roughly USD 80–100 per ton, with best cases down to USD 60–80. This is noteworthy because membranes usually struggle with such dilute flue gas.
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In coal plants, where CO₂ levels are higher, the membrane’s strong CO₂/N₂ selectivity cuts energy use and brings costs into the USD 25–50 per-ton range. Cement plants have more oxygen in their flue gas, which makes selectivity trickier, but the membrane still reaches similar cost ranges and stays stable across the different scenarios tested. Across all three sectors, the membrane’s high permeance keeps the required surface area small, which helps reduce the footprint of a full capture system.
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The study shows that pyridinic-graphene could offer a compact and potentially cost-effective alternative to solvent-based capture once scaled. It also points to areas where the material could still improve, especially its ability to distinguish CO₂ from oxygen in cement flue gas.
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